Here’s few screenshots of Dreamweaver CS 6 (version 12.0 build 5808) and Photoshop CS6 (version 13.0). By the way Dreamweaver CS 6 has no 64-bit version yet.
New Mini Bridge in the Photoshop:

Photography workspace:

Painting workspace:

Photoshop lightroom-alike dark interface:
Dreamweaver welcome screen:
Dreamweaver Fluid Grid Layout in the New document selection:
Dreamweaver multiscreen preview:

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Great looking screenshots of the interface of Photoshop. Dreamweaver looks nice too, but C’mon Adobe, give us the dark interface option on Dw as well.